پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Study on the Effects of Temperature, Time and the Policy of Prepolymerization on Particle Morphology in Propylene Slurry Polymerization with Heterogeneous
Ziegler-Natta Catalysts
مطالعه اثر دما، زمان و نحوه پیش پلیمر شدن بر شکل شناسی ذرات در پلیمر شدن دوغابی پروپیلن با کاتالیزورهای ناهمگن زیگلر- ناتا
417
428
734
10.22063/jipst.2007.734
FA
غلامرضا
پیرچراغی
سعید
پورمهدیان
مهدی
وطن خواه
Journal Article
2013
02
24
The effects of temperature, time and the strategy of prepolymerization were studied on the morphology of polypropylene particles. propylene polymerization was carried out in slurry phase using 4th generation of Ziegler-Natta Catalyst, cyclohexylmethyl dimethoxysilane as external electron donor, and triethyl aluminum as co-catalyst. Prepolymerizations were carried out based on two strategies: isothermal and non-isothermal conditions. Particle imaging using SEM, bulk density, and particle size distribution was used to analyse the particle morphology. It was found that the variation of initial condition together with the change in the mechanism of particle fracture has a dominant effect on particle morphology. Each combination between the temperature and reaction time causes to have a special effect on the product particle morphology. It has become clear that in isothermal prepolymerization, spherical particles with identical properties were produced. In low temperature experiments particles with porous surface were observed. At increasing temperature, however, the pores disappeared. Non-isothermal prepolymerization produced different morphological types. In all experiments coreshell structures were observed that seemed to be related to the structure of catalysts.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Solvent Texturing of Polyester Yarns Using Trichloroacetic Acid/Methylene Chloride
تغییر شکل شیمیایی نخ های پلی استر با استفاده از مخلوط حلال های تری کلرواستیک اسید - متیلن کلرید
429
436
775
10.22063/jipst.2007.775
FA
مهدی
نوری
کامران
محفوظی
Journal Article
2013
03
02
The effects of trichloroacetic acid/methylene chloride (TCAc/MC) on the mechanical properties and solvent texturing of polyester yarns are studied. The treatments are carried out in unstrained and strained states at different concentrations of TCAc for various treatment times. Breaking load and elongation-at-break of treated yarns have been recorded. Treatments of polyester yarns with TCAc/MC in unstrained state have increased the elongation-at-break without significant changes in breaking load, Whereas, treatments of the yarns in strained state improved breaking load without significant changes in elongation-at-break. Solvent texturing of polyester yarns using TCAc/MC has been performed by twisting-solvent setting-untwisting process. The effects of setting times and TCAc concentration on the permanent and reversible shrinkage of textured yarns have been examined. It was shown that the shrinkage and texturing properties of solvent treated yarns increased with increasing concentration of TCAc and setting time. The results are discussed on the basis of the fine structure of polyester yarns.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
The Study on Electrospinning of Nanofibers from Sodium Alginate and the Effects of Different Co-solvents
on Electrospinning of Polymer Solution
بررسی امکان تولید نانوالیاف از سدیم آلژینات به روش الکتروریسی و اثر کمک حلال های مختلف بر افزایش قابلیت الکتروریسی آن
437
447
776
10.22063/jipst.2007.776
FA
سمیه
صفی
مهران
غیاثی
محمد
مرشد
سید عبدالکریم
حسینی
Journal Article
2013
03
02
In the past decade, electrospinning as a facile and effective means in producing nanofibers with diameters ranging from microns down to a few nanometers has been developed and considered important. In this work, electrospinning of an interesting natural biopolymer, sodium alginate, has been investigated. The results showed that water solution of sodium alginate cannot be electrospun into nanofibers. Moreover, using different organic solvents and surfactants did not help the spinnability of the polymer solution. To improve the solubility of the polymer in organic solvents, we used ammonium alginate or alginic acid instead of sodium alginate, but the results were not satisfactory. However, we were able to electrospin the sodium alginate from aqueous solution by blending it with a synthetic polymer, poly(ethylene oxide) (PEO). The type of interactions between sodium alginate and PEO was examined by FTIR. The morphology and diameter of the electrospun fibers were observed and determined by using an optical microscope and a scanning electron microscope (SEM). The measurement of solution properties such as viscosity showed a strong dependence of spinnability and fiber morphology on solution viscosity and thus on alginate-to-PEO blend ratios.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Investigation of Contact Poling Process in Thin Films of Polymer Doped with Disperse Red 1 Dye
بررسی فرایند ایجاد نظم با الکترودهای تماسی در لایه های نازک پلیمری دوپه شده با رنگینه Disperse Red ۱
449
455
777
10.22063/jipst.2007.777
FA
عزالدین
مهاجرانی
محمدهاشم
رضوانی
راضیه
محزون
Journal Article
2013
03
02
Thin films of polymer doped with nonlinear optical organic dye, Disperse Red 1, at thickness of 1 to 2 micrometers, were prepared and studied. In order to induce an axial and orientational alignment of dye molecules within polymer matrix, a contact electric field poling was used. By this process the inherent inversion symmetry in the polymer matrix was eliminated to achieve the desired macroscopic second order nonlinear optical response. With a method based on spectroscopy, poling process and parameters related to orientation were studied. Different parameters such as temperature and residual solvent effects and also temporal and spatial dependencies were investigated and analyzed.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Determination of the Optimum Conditions for Production of Chitosan Nanoparticles
تعیین شرایط بهینه تهیه نانوذرات از پلیمر طبیعی کیتوسان
457
464
778
10.22063/jipst.2007.778
FA
امیر
دوستگانی
ابراهیم
واشقانی فراهانی
محمد
ایمانی
Journal Article
2013
03
02
Bioedegradable nanoparticles are intensively investigated for their potential applications in drug delivery systems. Being a biocompatible and biodegradable polymer, chitosan holds great promise for use in this area. This investigation was concerned with determination and optimization of the effective parameters involved in the production of chitosan nanoparticles using ionic gelation method. Studied variables were concentration and pH of the chitosan solution, the ratio of chitosan to sodium tripolyphosphate therein and the molecular weight of chitosan. For this purpose, Taguchi<br />statistical method was used for design of experiments in three levels. The size of chitosan nanoparticle was determined using laser light scattering. The experimental results showed that concentration of chitosan solution was the most important parameter and chitosan molecular weight the least effective parameter. The optimum conditions for preparation of nanoparticles were found to be 1 mg/mL chitosan solution with pH=5, chitosan to sodium tripolyphosphate ratio of 3 and chitosan molecular weight of 200,000 daltons. The average nanoparticle size at optimum conditions was found to be about 150 nm.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Effects of Decalin on Some Properties of Polypropylene Continuous Filaments
اثر دکالین بر خواص رشتههای مداوم پلیپروپیلن
465
479
779
10.22063/jipst.2007.779
FA
طاهره
معینی
محمد
حقیقت کیش
Journal Article
2013
03
02
This work has setup to determine the effects of a solvent on the structure and properties of polypropylene fibres with different physical structures. Samples of continuous filament yarns with different physical structures (partially oriented (POY) and drawn yarns) are treated with decahydronaphthalene (decalin) at 28, 55, 75 and 95oC. At 95oC, the samples are dissolved completely in decalin and after cooling to room temperature (28oC), only 94% of the polypropylene precipitated. The results of the treating yarn samples with decalin at 28, 55 and 75oC, show a small reduction in the weight of the samples. Breaking strength and elongation remained unchanged and stress-strain curve of the POY samples in the yield region did not change. Fourier transform infrared spectra of the samples are compared with those of the published literature and the changes in the spectrum as the results of the treatment with decalin are verified. X-ray diffraction studies show the changes in the structure of POY samples. Differential scanning calorimeter shows no changes in the melting point of the samples, but confirms the results of X-ray diffraction regarding the changes in the structure of POY samples. For the drawn samples X-Ray diffraction diagrams did not show considerable changes. Measurement of birefringence of the samples shows considerable changes in the molecular orientation of the samples due to solvent treatment. The changes in the structure of the samples treated at low temperature with decalin are explained with reference to the pertinent structural models of polypropylene fibers.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Study of the Effect of Murray Red Gum Tree Age on Chemical Components and Cellulose Degree of Polymerization
اثر سن درخت بر ترکیبات شیمیایی و درجه پلیمرشدن سلولوز
481
488
780
10.22063/jipst.2007.780
FA
علیرضا
شاکری
احسان
کبیری
سید ضیاءالدین
حسینی
Journal Article
2013
03
02
This research was performed to study the effect of Murray red gum tree age (4, 6, 8 years) on the chemical components, viscosity and the cellulose degree of polymerization. The Eucalyptus trees were cut at the ages of 4, 6, and 8 from hand planted forests. The contents of cellulose, hemicellulose, lignin, extractives and ash for each age were then determined. The results show that with increasing age the contents of cellulose, hemicellulose and lignin increased but the extractives and ash contents decreased. After measuring the viscosity of cellulose solution, the degree of polymerization<br />(DP) was also determined by using the standard equation. The viscosity numbers for 4, 6 and 8 year old trees were 290, 503 and 566 mL/g, respectively, and the DP were 272, 568 and 652, respectively. Finally after analyzing and comparing the results, the age of 8 was found to have best properties for viscose industry. But in order to reduce the forestry and production costs, 6 year old tree instead of 8 could be cut because of the close results in DP and cellulose content.
پژوهشگاه پلیمر و پتروشیمی ایران با همکاری انجمن پلیمر ایران
مجله علوم و تکنولوژی پلیمر
10163255
20
5
2007
12
22
Mechanical Properties of Non-Woven Polyester Fibers and Polymer-Modified Bitumen Composites
خواص مکانیکی کامپوزیت های الیاف نبافته پلی استر و قیر پلیمری
489
502
781
10.22063/jipst.2007.781
FA
وحید
حدادی
علی اکبر
یوسفی
تقی
گنجی
مرتضی
خسروی
Journal Article
2013
03
02
Blown bitumen (110/10) was mixed with heavy vacuum slops (H.V.S), 60/70 penetration grade bitumen and recycled isotactic polypropylene (iPP) at different levels. The resulting resins were used to impregnate non-woven poly(ethylene terephthalate) fibers to form composites. The modulus and penetration grade of the resulting bituminous resins were determined. It was found that these bituminous resins drastically affect the modulus of the composites formed by low-Young’s modulus fibers such as polyesters. Consequently, interactions between resin and fibers and the correlation length of asphalthenes (in absence of iPP) and interdiffused coalescence and segregated network of asphalthenes (in presence of iPP) result in a non-linear behavior of composite’s modulus. The behavior of the composites with or without iPP is controlled by resin toughness and resin interactions with the fiber through the viscosity. Comparison of the experimental composite modulus data with the theoretical modulus data revealed that the Takayanangi’s model best predicts the behavior of these composites. The adjustment factors of this model were reported and proposed as an indication of fiber-resin interaction. It was also found that the modulus of fibers is affected by toughness, viscosity and the iPP content of the bituminous resin.