The Effect of non-Newtonian Behavior of Fluid on the Tubular Reactor Performance and Studying Different Variables in Relation to the Degree of Conversion

Document Type : Research Paper

Authors

Department of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, P.O. Box: 179, Ardabili, Iran

Abstract

In tubular reactors, there are different parameters which can affect the degree of conversion. The type of fluid motion and velocity profile of substances in the reactor are of most central measures. Different rheological models can be employed to study the behavior of fluids; power law model is one of the most commonly used models. In this study, the rheological behaviour of polymerization reaction of methyl methacrylate was examined. Due to the similarity function of tubular and batch reactors, the number of test tubes are used to prepare the solution. After preparation of the reactor solution, the n value of power law model was estimated within the span of 0.3492 to 0.9889 by curve fitting. Employing these rheological data, a reactor has been designed. Moreover, the effects of parameters such as reaction temperature, initiator wt%, the concentration of monomer and reactor’s radius on the degree of conversion have been studied. The obtained results in the research indicate a direct proportionality of conversion with the reaction temperature, initiator wt% and the concentration of monomer and also an inverse proportionality of conversion with reactor’s radius. Finally, the amount of conversion was obtained equal to 56.47% and according to its laboratory proportion which was 55.88% we have reached the conclusion that the modeling duly undertaken is applicable and valid.

Keywords

Iranian Journal of Polymer Science and Technology
Volume 27, Issue 6 - Serial Number 6
March and April 2015
Pages 436-423

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