بهبود عملکرد غشای نانوفیلتری لایه‌نازک پلی‌آمیدی با نانولوله‌های اصلاح‌شده تیتانیم اکسید

نوع مقاله : پژوهشی

نویسندگان

1 بابل، دانشگاه صنعتی نوشیروانی بابل، دانشکده مهندسی شیمی، صندوق پستی 484

2 اسکودای، جوهور، دانشگاه صنعتی مالزی، مرکز تحقیقاتی فناوری‌های‌ نوین غشایی

چکیده

فرضیه: امروزه غشاهای نانوفیلتری به‌طور گسترده در زمینه نمک‌زدایی و تصفیه آب به‌کار گرفته می‌شوند. اما، باید برخی مشکلات شایان توجه در زمینه نمک‌زدایی از قبیل شار و پس‌زنی کم را با کاربرد نانومواد اصلاح‌شده کنترل کرد. پژوهش‌های مختلفی در این زمینه انجام شده است، اما اهمیت موضوع، انجام پژوهش‌های بیشتر را در این زمینه ضروری می‌کند.
روش‌ها: غشاهای نانوکامپوزیتی لایه‌نازک دارای نانولوله‌های تیتانیم اکسید و نیز نانولوله‌های تیتانیم اکسید اصلاح‌شده بررسی شدند. بدین ترتیب که پس از تهیه نانولوله‌ها، سطح داخلی آن‌ها اصلاح و پس از تهیه غشا، مقدار تراوایی (عبوردهی) آب و پس‌زنی یون‌های تک و دوظرفیتی به‌وسیله غشا اندازه‌گیری شد. همچنین، نانولوله‌های اولیه و اصلاح‌شده با طیف‌سنجی زیرقرمز تبدیل فوریه (FTIR) و آزمون اندازه‌گیری سطح ویژه (Brunauer-Emmett-Teller, BET) بررسی شدند. شکل‌شناسی و ساختار غشاهای لایه نازک با میکروسکوپی الکترونی پویشی نشر میدانی (FE-SEM) ارزیابی شد.
یافته‌ها: عملکرد غشاهای لایه‌نازک پلی‌آمیدی با آزمون‌های تراوایی آب خالص، زاویه تماس، شار تراوایی خوراک و مقدار پس‌زنی یون‌های سدیم و مس ارزیابی شد. بیشینه مقدار شار آب خالص (26.5L/m2h) برای غشا دارای %0.05 وزنی نانولوله اصلاح‌نشده، با %73.2 افزایش در مقایسه با غشای خالص به‌‌دلیل آب‌دوستی نانولوله‌ها و ایجاد منفذهای کوچک در سطح غشا به‌دست آمد. بیشینه پس‌زنی یون سدیم (%93.11) برای غشا دارای %0.2 وزنی نانولوله اصلاح‌شده به‌دلیل کاهش قطر نانولوله‌های اصلاح‌شده و تأمین سد انرژی لازم برای پس‌زنی نمک‌ها به‌دست آمد.

کلیدواژه‌ها

عنوان مقاله [English]

Improvement in Polyamide Thin Film Nanofiltration Membrane Performance with Modified Titanium Oxide Nanotubes

نویسندگان [English]

  • Zeinab Fallahnejad 1
  • Gholamreza Bakeri Jafarkolaei 1
  • Ahmad Fauzi Ismail 2
1 Faculty of Chemical Engineering, Babol Noshirvani University of Technology, P.O. Box 484, Babol, Iran
2 Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Darul Takzim, Malaysia
چکیده [English]

Hypothesis: Nowadays, nanofiltration membranes are used extensively in desalination and water treatment, but some major drawbacks in the desalination such as low flux and rejection should be handled through application of modified nanomaterials. A number of research works have been done in this field but the importance of the subject makes more studies in this field indispensable.
Methods: Thin film nanocomposite membranes containing titanium oxide nanotubes and modified titanium oxide nanotubes were evaluated in this study which after synthesis of the nanotubes, their inner surface was modified and after synthesizing the membranes, the membranes’ water permeability and rejection of the monovalent and divalent ions were measured. Furthermore, Fourier transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) tests were used to study the neat and modified nanotubes. Field emission scanning electron microscopy (FE-SEM) analysis was used to study the morphology and structure of these thin film membranes.
Findings: The performance of polyamide thin film membranes was evaluated by pure water permeation test, contact angle test, permeation flux of the feed and rejection of sodium and copper ions. Due to the hydrophilicity of the nanotubes and formation of small pore on the membrane surface, the maximum pure water flux (26.5 L/m2h) was obtained for the membrane containing 0.05% (wt) unmodified nanotube; an increase of 73.2% compared to its neat membrane. Due to the reduced diameter of the modified nanotubes and providing sufficient energy barrier for the salts to be rejected, the maximum sodium ion rejection (93.11%) was obtained for the membrane containing 0.2% (wt) modified nanotubes.

کلیدواژه‌ها [English]

  • nanofiltration membrane
  • nanotube
  • titanium oxide
  • permeation
  • rejection

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مجله علوم و تکنولوژی پلیمر
دوره 33، شماره 4 - شماره پیاپی 168
مهر و آبان 1399
صفحه 291-304

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